|
|
3-epi-6-deoxocathasterone + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 6-deoxotyphasterol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-11531
|
|
|
|
campesterol + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (22S)-22-hydroxycampesterol + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-4225
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 3-dehydro-6-deoxoteasterone + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
| |
MetaCyc:
RXN-11101
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + NADP+ <=> H+ + (22S)-22-hydroxycampest-4-en-3-one + NADPH
|
1.3.1
1.3.1.22
3-oxo-5alpha-steroid 4-dehydrogenase (NADP+)
|
–
–
|
| |
KEGG:
R07447
MetaCyc:
RXN-4229
|
|
|
|
campesterol + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 6-deoxocathasterone + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-773
|
|
|
|
3-epi-6-deoxocathasterone + acceptor <=> reduced_acceptor + (22S,24R)-22-hydroxy-5alpha-ergostan-3-one
|
1.1.99.M2
|
–
|
| |
MetaCyc:
RXN-11532
|
|
|
|
5alpha-campestan-3-one + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (22S,24R)-22-hydroxy-5alpha-ergostan-3-one + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-4230
|
|
|
|
(24R)-ergost-4-en-3-one + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (22S)-22-hydroxycampest-4-en-3-one + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-4231
|
|
|
|
6-deoxoteasterone + acceptor <=> 3-dehydro-6-deoxoteasterone + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-775
|
|
|
|
campesterol <=> Campest-4-en-3beta-ol
|
5.3.3.1
steroid Delta-isomerase
|
–
|
| |
KEGG:
R07427
MetaCyc:
RXN-709
|
|
|
|
(22S)-22-hydroxycampesterol + acceptor <=> (22S)-22-hydroxycampest-4-en-3-one + reduced_acceptor
|
1.1.99.M1
|
–
|
| |
MetaCyc:
RXN-4226
|
|
|
|
(22S)-22-hydroxycampesterol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (22R,23R)-22,23-dihydroxycampesterol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-11529
|
|
|
|
6-deoxocathasterone + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 6-deoxoteasterone + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-774
|
|
|
|
Campest-4-en-3beta-ol + NAD+ <=> (24R)-ergost-4-en-3-one + NADH + H+
|
1.1.1.357
3alpha-hydroxysteroid 3-dehydrogenase
|
–
|
| |
KEGG:
R07428
MetaCyc:
RXN-710
|
|
|
|
6-deoxotyphasterol + acceptor <=> 3-dehydro-6-deoxoteasterone + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-776
|
|
|
|
3-dehydro-6-deoxoteasterone + acceptor <=> (22R,23R)-22,23-dihydroxycampest-4-en-3-one + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-11534
|
|
|
|
(22S)-22-hydroxycampest-4-en-3-one + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (22R,23R)-22,23-dihydroxycampest-4-en-3-one + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-11530
|
|
|
|
(22R,23R)-22,23-dihydroxycampesterol + acceptor <=> (22R,23R)-22,23-dihydroxycampest-4-en-3-one + reduced_acceptor
|
1.1.99.M3
|
–
|
| |
MetaCyc:
RXN-11533
|
|
|
|
campesterol + acceptor <=> 5alpha-campestan-3-one + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-712
|
|
|
|
5alpha-campestan-3-one + NADP+ <=> H+ + (24R)-ergost-4-en-3-one + NADPH
|
1.3.1
1.3.1.22
3-oxo-5alpha-steroid 4-dehydrogenase (NADP+)
|
–
–
|
| |
KEGG:
R07429
MetaCyc:
RXN-711
|
|
|
|
6-deoxocathasterone + acceptor <=> (22S,24R)-22-hydroxy-5alpha-ergostan-3-one + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-4228
|
|
